The oil yield was approximately 44%, which is in agreement with the literature (BHATTI, IA; ASHRAF, S . 368 p.), o que necessitaria de uma menor quantidade de rea plantada para suprir a demanda de combustvel (biodiesel) da mesma proporo que a soja.7/7 [020] Horse peanuts become more attractive as a fuel source (biodiesel), because their yield can reach an average of 45-50%, an average of 1059 liters of oil per hectare, while soy, a The most widely used oilseed for the production of biodiesel has a lipid content of around 20%, an average of 446 liters of oil per hectare (PAHL, GREG; foreword by McKIBBEN, BILL. : C10L 1/02; C07C 67/03 (52) CPC: C10L 1/02,C07C 67/03 (73) Titular(es): UNIVERSIDADE FEDERAL DA GRANDE DOURADOS (72) Inventor(es): EURPEDES GARCIA SILVEIRA JUNIOR; EUCLSIO SIMIONATTO; NESTOR ANTONIO HEREDIA ZARATE (57) Resumo: PROCESSO DE, CARACTERIZAO DO LEO DE ALQUILSTERES (BIODIESEL), a presente inveno, um processo de extrao, caracterizao e produo de steres a partir da cultivar de amendoim-cavalo (Arachis hypogaea var. A chemical modification of high molecular mass triglycerideswhere some of the long fatty acid chains are replaced with a short acetyl chainhas also been suggested to lower the viscosity of virgin oils [2273]. 28497,178 Geothermal fluid means water in any form at temperatures greater than 120. Applied Radiation and Isotopes. Os cidos graxos presentes no leo foram identificados utilizando um modelo[019] The oil was characterized by gas chromatography, using a chromatograph model HP-5890, with a column DB1 (J&W Scientific) 100% polymethylsiloxane, 60 m long x 0.25 mm internal diameter x 0.25 mm film thickness. Biodiesel, n - a fuel comprised of mono-alkyl esters of long chain fatty acids derived from vegetable oils or animal fats, designated B100, and meeting the requirements of ASTM D 6751. Good engineering practice (GEP) stack height means the greater of: Diatomaceous earth filtration means a process resulting in substantial particulate removal in which a precoat cake of diatomaceous earth filter media is deposited on a support membrane (septum), and while the water is filtered by passing through the cake on the septum, additional filter media known as body feed is continuously added to the feed water to maintain the permeability of the filter cake. Biodiesel: growing a new energy economy. [018] For the production of alkyl esters (biodiesel), horse peanuts were used, a variety of peanuts, whose planting and sowing is in a period of 7 (seven) months, had their shells removed manually to eliminate impurities, in they were then crushed with the aid of an industrial (homemade) processor. 65514,344 [003] E percebido que cada modelo de reao produz produtos com composio qumicas diferentes, como da US 2005/0029843 Al- Process For Transesterification on Fat And/Or Oil By Heterogeneous Catalysis, Jan.27/2005 - que um leo de origem biolgica pode ser transesterificado na presena de um catalisador que consiste de sal metlico de amino cido bsico ou cido derivativo. O leo foi caracterizado por cromatografia em fase gasosa (CG), onde determinou a composio dos cidos graxos do leo e dos steres. Esse processo possui a vantagem de ser inovador pelo fato de a reao ocorrer com o xido puro (97%).KNO3 / MgO Catalyst. 32,073 Esses estudos podem ser comprovados de acordo com LIU, 2007 (LIU, X.; HE, H.; WANG, Y.; ZHU, S. Transesterification of soybean oil to biodiesel using SrO as a solid base catalyst. REFERENTE A 4A ANUIDADE. These feedstocks are also potentially more sustainable than agricultural crops. O rendimento do leo foi de aproximadamente 44%, o que esta de esta acordo com a literatura (BHATTI, I. os cidos graxos majoritrios foram o cido oleico, linoleico e palmtico, sendo que esses compreendem um total de aproximadamente 85% do total da composio qumica dos leos. Studies were carried out to obtain biodiesel from oil through transesterification reactions. 6/10Petition 870180015895, of 02/27/2018, p. 6/10. I am good at research and analysis I also have some soft skills such as problem solving or critical thinking , I know how to optimize designs and do numerical analysis . A variety of peanuts evaluated as a possible alternative source for the production of biodiesel. Temporary clean coal technology demonstration project means a clean coal technology demonstration project that is operated for a period of five years or less and that complies with the SIP and other requirements necessary to attain and maintain the national ambient air quality standards during the project and after the project is terminated. In the remainder of this paper, we use the term biodiesel in its conventional scope, limited to mono alkyl ester fuels. I am doing chemical engineering from Uet I am also the media secretary of AIChE, student ambassador, and digital marketer. 4,1167 Resources. Higher order alcohols such as ethanol and propanol can also be used in the production of mono alkyl esters. Depending on the feedstock, biodiesel may be referred to by a number of more specific terms and corresponding acronyms, the most common ones being: In France, biodiesel fuelmostly rape methyl esteris also referred to as diester. The most common alcohol used in the production of mono alkyl esters is methanol and the more specific label methyl ester is often attached to this type of esterified biodiesel. Os resultados foram satisfatrios, podendo ser constatado pelas tcni()CHARACTERIZATION OF THE ALKYLESTERS OIL (BIODIESEL), the present invention, is a process of extraction, characterization and production of esters from the horse peanut cultivar (Arachis hypogaea var. 4/10. Demand for palm oil is therefore likely to continue all over the world, in spite of the negative association of palm oil plantations with deforestation and environmental degradation of large areas of tropical forest. 49,983 Lignocrico Geothermal fluid means water in any form at temperatures greater than 120. Concentrao Virgnia L.) atravs da catlise heterognea utilizando xido de magnsio puro (MgO 97%). Composio dos cidos graxos presentes no leo de amendoim-cavaloTable 1. Methods have also been developed to make diesel fuel substitutes from oils naturally produced by certain species of algae [495]. [005] It has been demonstrated that in all processes each reaction model produces products with different chemical composition and have high production costs, common catalysts are discarded after the reaction, causing a high level of corrosion in the ignition engines and particulate matter. Virgnia L.) atravs da catlise heterognea utilizando xido de magnsio puro (MgO 97%). - xido de magnsio de 5,0% a 10,0% de quantidade em relao quantidade de leo do amendoim-cavalo. [011] The process, according to the present invention, presents figures and equations to facilitate its description. Ultra Low Sulfur Diesel Fuel means diesel fuel that has a sulfur content of no more than fifteen parts per. Por fim os frascos foram expostos a um banho de leo, sendo qualquer tipo de leo; de soja, girassol ou milho, por 1 hora na temperatura de 65 C. Grenoble (/ r n o b l / gr-NOH-bl, French: [nbl] (); Arpitan: Grenoblo or Grainvol; Occitan: Graanbol) is the prefecture and largest city of the Isre department in the Auvergne-Rhne-Alpes region of southeastern France. Os cidos graxos majoritrios foram o cido oleico, linoleico e palmtico, sendo que esses compreendem um total de aproximadamente 85% do total da composio qumica dos leos. 0.9485, Petio 870180015895, de 27/02/2018, pg. 28497,178 Plantations for biodiesel production were started in India and in some African countries [1159]. 276076.906 (08: 1) - ativao em mufla a 300 C por 4 horas. 32,073 2. ed. Manufacturing operation means a process in which materials are changed, converted, or transformed into a different state or form from which they previously existed and includes refining materials, assembling parts, and preparing raw materials and parts by mixing, measuring, blending, or otherwise committing such materials or parts to the manufacturing process. Ethanol means a high octane gasoline blend stock that is used to make various grades of gasoline. Procedia Environmental Sciences v. 11, p. 757 762, 2011.) Biodiesel, defined as the mono-alkyl esters of vegetable oils or animal fats, is an balternativeQ diesel fuel that is becoming accepted in a steadily growing number of countries around the world. "Manufacturing operation" does not include packaging. In the third stage, the tetrahedral intermediate takes H + from the surface of the MgO (Eq. In the last stage, the rearrangement of the tetrahedral intermediate results in the formation of biodiesel. A process of preparing alkyl esters of free fatty acids, including, but not limited to, biodiesels is described herein. Background: Biodiesel is a mixture of fatty acid short-chain alkyl esters of different fatty acid carbon chain lengths. Methyl or ethyl esters were produced from lard and restaurant grease by lipase- or base-catalyzed reactions. Diatomaceous earth filtration means a process resulting in substantial particulate removal in which a precoat cake of diatomaceous earth filter media is deposited on a support membrane (septum), and while the water is filtered by passing through the cake on the septum, additional filter media known as body feed is continuously added to the feed water to maintain the permeability of the filter cake. 239944,000 [017] A Figura 6 apresenta Equaes do Mecanismo de Transesterificao do leo de amendoim-cavalo com xido de magnsio: A Equao 1 forma a superfcie CH30-. 76,383 2), onde Ri representa o grupo de alquila de Cadeia de registro. ; HAMA, S.; TAMALAMPUDI, S.; NODA, H. Whole-cell biocatalysts for biodiesel fuel production. ANULADA A PUBLICACAO CODIGO 8.6 NA RPI NO 2595 DE 29/09/2020 POR TER SIDO INDEVIDA. Under the same convention, neat biodiesel is termed B100. For this purpose, the first database contained 1231 densities of 58 alkyl esters, while the second covered 696 densities of 16 pure biodiesel samples and 8 biodiesel blends. PTO PTO PDF Espace: Google: link PDF PAIR: Patent. 239944,000 Qumica Nova, v.30, n.3, p. 667 676 2007.) Oil from jatropha (Jatropha curcas) nuts was considered as a potential biodiesel feedstock in tropical climates in the early years of the 21 century because jatropha plants tolerate poor, degraded soils and are resistant to pest and disease. It must be emphasized that unprocessed or partially esterified vegetable oilsunless specifically accommodated for in the engine designare generally considered unsuitable as diesel fuels and do not meet the requirements set by existing biodiesel standards and specifications. Estados Unidos da Amrica, USA: Chelsea Green Publishing Company, 2008. virginia l.) atravs da catlise heterognea utilizando xido de magnsio puro (mgo 97%). [004] Um processo de fabricao de biodiesel, conhecido, da BR PI0507963-2 A - PROCESSO DE FABRICAO DE BIOCOMBUSTVEIS; TRANSFORMAO DE TRIGLICERDEOS EM PELO MENOS DUAS FAMLIAS DE BIOCOMBUSTVEIS:[004] A biodiesel manufacturing process is known from BR PI0507963-2 A - BIOFUELS MANUFACTURING PROCESS; TRANSFORMATION OF TRIGLYCERIDES INTO AT LEAST TWO FAMILIES OF BIOFUELS: Petio 870180015895, de 27/02/2018, pg. After 24 h of reaction, 96% conversion was obtained, while only 25% conversion was observed from crude grease. 47,4368 Cl. The alkyl ester oil (biodiesel) characterization process, the present invention, is a process of extracting, characterizing and producing esters from the horse peanut cultivar (arachis hypogaea var. 132846,094 Diesel engine means an engine which works on the compression-ignition principle. can be accepted as biodiesel, this nal product must meet stringent quality requirements (the European standard EN14214 or the USA standard ASTM D6751). Dyed diesel fuel means diesel fuel that meets the dyeing and marking requirements of 26 U.S.C. Catalysis Communications, v. 8, p 1107 - 1111, 2007.). Tetrahedron, 66, p. 4257 4264, 2010), catlise bsica (SUAREZ, P. A. The temperature of the Split injector was 280 C and the detector temperature was 300 C. The heating ramp of the column was initially maintained at a temperature of 50 C per minute, after which it was heated at a rate of 10 C per minute 1 to 250 C, remaining at this temperature for 10 minutes. Transit-oriented development means infrastructure improvements that are located within 1/2 mile of a transit station or transit-oriented facility that promotes transit ridership or passenger rail use as determined by the board and approved by the municipality in which it is located. Biodiesel feedstocks can include vegetable oils, rendered animal fats, algae oils as well as used cooking oils and greases. Biodiesel fuel means a fuel that is comprised of mono- alkyl esters of long chain fatty acids derived from vegetable oils or animal fats. e catlise heterognea, utilizada nesta patente de inveno. 2. ed. 7/7 [020] O amendoim-cavalo se toma mais atrativo como fonte de combustveis (biodiesel), por que seu rendimento pode alcanar em mdia 45-50%, em mdia de 1059 litros de leo por hectare, enquanto a soja, uma oleaginosa mais utilizada para a produo de biodiesel possui um teor lipdico em tomo de 20%, em mdia de 446 litros de leo por hectare (PAHL, GREG; foreword by McKIBBEN, BILL. At the time this definition was developed, alkyl esters began to receive significant attention and were the only fuel that was considered to carry the label biodiesel. A presente inveno esta includa como tecnologia verde, e possui vantagens em relao s reaes convencionais, pois os catalisadores podem ser reciclados aps a reao, no contm gua menos corrosivo e quando o combustvel queimado nos motores por ignio emite menos matrias particuladas. Eventually, biodiesel research focused on alkyl esters due to their superior properties. ; ZHU, S. Transesterification of soybean oil to biodiesel using SrO as a solid base catalyst. [003] E percebido que cada modelo de reao produz produtos com composio qumicas diferentes, como da US 2005/0029843 Al- Process For Transesterification on Fat And/Or Oil By Heterogeneous Catalysis, Jan.27/2005 - que um leo de origem biolgica pode ser transesterificado na presena de um catalisador que consiste de sal metlico de amino cido bsico ou cido derivativo. Cl. A temperatura do injetor Split foi de 280C e a temperatura do detector foi de 300C. 308655,656 Data were collected using the CLASS-CR10 Software. 3/10Petition 870180015895, of 02/27/2018, p. 3/10. The blends are often designated by a capital B followed by biodiesel percentage (by volume) in the blend. Peaks Studies were carried out to obtain biodiesel from oil, through transesterification reactions. Biodiesel is defined as a fuel comprised of mono-alkyl esters of long chain fatty acids derived from vegetable oils or animal fats, either in pure form or mixed in any combination with petroleum-based diesel fuel. A Figura 1 mostra o aparato experimental para a extrao do leo do amendoim-cavalo. [013] A Figura 3 demostra o cromatograma da composio de cidos graxos presentes no leo de amendoim-cavalo. 4.3779 2), where Ri represents the alkyl chain chain group. A Equao 2 forma um intermedirio tetradico do tomo de carbono da carbonila da molcula de Equation 2 forms a tetrahedral intermediate of the carbonyl carbon atom of the, Petio 870180015895, de 27/02/2018, pg. 5/7 triglicerdeos atrai um nion metxido da superfcie do MgO, onde RI representa o grupo de alquila de Cadeia de registro. Free format text: Dictionary. virginia l.) through heterogeneous catalysis using pure magnesium oxide (mgo 97%). The oil phase containing the biodiesel was, Petio 870180015895, de 27/02/2018, pg. 76,383 [007] Sendo assim, a presente inveno teve como objetivo produo do biodiesel, a partir do leo de amendoim-cavalo atravs da reao de transesterificao pela catlise heterognea, utilizando o xido de magnsio (MgO) comercial. Priority. 4/7 extrada com n-hexano, seca em MgSO4, pesada, analisada por cromatografia gasosa (CG-FID). PROCESSO DE CARACTERIZAO DO LEO DE ALQUILSTERES (BIODIESEL) [001] A presente inveno diz respeito a um processo de extrao, caracterizao e produo de steres a partir da cultivar de amendoimcavalo (Arachis hypogaea var. Finally, the bottles were exposed to an oil bath, being any type of oil; soy, sunflower or corn, for 1 hour at a temperature of 65 C. After the reaction period, the flasks were removed from the system, cooled and the catalyst was separated by decantation and centrifugation. After 24 h of reaction, 96% conversion was obtained, while only 25% conversion was observed from crude grease. These studies can be confirmed according to LIU, 2007 (LIU, X . 41,923 ; HE, H . A.; ASHRAF, S.; SHALID, M. Quality index of oils extracted from Dirradiated peanuts (Arachis hypogaea L.) of the golden and bari varieties. 49,983 9313,931 1244128,750 TME was prepared at an optimized . 44,803 Regenerated restaurant grease (FFA removed through column chromatography) was further converted to esters by alkali-catalyzed methanolysis. Estados Unidos da Amrica, USA: Chelsea Green Publishing Company, 2008. o leo foi caracterizado por cromatografia em fase gasosa (cg), onde determinou a composio dos cidos graxos do leo e dos steres. 1 lipid transesterification using response surface methodology and analytical characterization of biodiesel, Publication of a patent application or of a certificate of addition of invention [chapter 3.1 patent gazette], Dismissal acc. Your email address will not be published. Thumba oil with a higher triglyceride content can be a promising feed for synthesizing a fatty acid alkyl ester as an alternative to pure diesel. Alkyl esters produced in this study could be used for fuels, potentially as biodiesel. uma variedade de amendoim avaliada como uma possvel fonte alternativa para a produo de biodiesel. 7767839. Results depict CD to be a promising candidate to replicate the conversion and product purity of conventional biodiesel processes while having significant savings in capital (41.42% cheaper than the conventional process) and utility (18.12% less than the conventional process) costs, thereby making it a very competitive alternative. A equao 3 formao quando intermedirio tetradrico pega H+ da superfcie do MgO. Palmtico Trends in Biotecnology, vol. Esse processo possui a vantagem de ser inovador pelo fato de a reao ocorrer com o xido puro (97%). : C10L 1/02; C07C 67/03 (52) CPC: C10L 1/02, C07C 67/03 (73) Holder (s): FEDERAL UNIVERSITY OF GRANDE DOURADOS (72) Inventor (s): EURPEDES GARCIA SILVEIRA JUNIOR; EUCLSIO SIMIONATTO; NESTOR ANTONIO HEREDIA ZARATE (57) Abstract: PROCESS OF, CARACTERIZAO DO LEO DE ALQUILSTERES (BIODIESEL), a presente inveno, um processo de extrao, caracterizao e produo de steres a partir da cultivar de amendoim-cavalo (Arachis hypogaea var. Z.; MENEGHETTI, S. . The chapter further provides answers to why vegetable oils and animal fats are transesterified to alkyl esters (biodiesel) and why vegetable oils, animal fats, and their derivatives can be used as (alternative) diesel fuel. This process has the advantage of being innovative due to the fact that the reaction occurs with pure oxide (97%). Nuclear fuel cycle-related research and development activities means those activities which are specifically related to any process or system development aspect of any of the following: - conversion of nuclear material, - enrichment of nuclear material, - nuclear fuel fabrication, - reactors, - critical facilities, - reprocessing of nuclear fuel, - processing (not including repackaging or conditioning not involving the separation of elements, for storage or disposal) of intermediate or high-level waste containing plutonium, high enriched uranium or uranium-233, but do not include activities related to theoretical or basic scientific research or to research and development on industrial radioisotope applications, medical, hydrological and agricultural applications, health and environmental effects and improved maintenance. 3), and can also react with methanol to generate methoxide anions (Eq. 5/10Petition 870180015895, of 02/27/2018, p. 5/10. From the commercial point of view, palm oil is particularly attractive because its yield per unit area of land is much higher than that of soy, rapeseed or other crops. 1 Solvente + C4:0; 2: C6:0; 3: C8:0; 4:00:0; 5:01:0; 6:02:0; 7: 03:0; 8:04:0; 9:04:1; 10:05:0; 11:05:1; 12: 06:0; 13:06:1; 14: 07:0; 15: 07:1; 16:08:0; 17: C18:lt9; 18: C18:ln9; 19: C18:2t9; 20: C18:2n6; 21:C18:3n6; 22:C20:0; 23: C18:3n3; 24: C20:ln9; 25: C21:0; 26:C:2n6; 27: C20:3n6; 28: C22:0; 29: C20:3n3 + C20:4n6; 30: C23:0.
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